The amphipod Talitrus saltator as a bioindicator of human trampling on sandy beaches     

Ugolini A  Ungherese G  Somigli S  Galanti G  Baroni D  Borghini F  Cipriani N  Nebbiai M  Passaponti M  Focardi S 《Marine environmental research》2008,65(4):349-357

The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.  相似文献   

Generalized Laplace coefficients and Newcomb derivatives     

Maurizio M. D’Eliseo 《Celestial Mechanics and Dynamical Astronomy》2007,98(2):145-154

It is shown how the generalized Laplace coefficients can be employed to deduce explicit formulas for ordinary and Newcomb derivatives of the Laplace coefficients.   相似文献   

A Fe K-edge XAS study of amethyst     

Francesco Di Benedetto  Francesco D’Acapito  Gabriele Fornaciai  Massimo Innocenti  Giordano Montegrossi  Luca A. Pardi  Silvia Tesi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2010,37(5):283-289

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.  相似文献   

Description of soils based on geomechanical criteria for improved landslide classification     

Gianfrancesco Rocchi  Giovanni Vaciago  Alberto Callerio  Maurizio Fontana  Riccardo Previtali 《Landslides》2014,11(5):813-825

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Human alteration of groundwater–surface water interactions (Sagittario River,Central Italy): implication for flow regime,contaminant fate and invertebrate response     

Mariachiara Caschetto  Maurizio Barbieri  Diana M. P. Galassi  Lucia Mastrorillo  Sergio Rusi  Fabio Stoch  Alessia Di Cioccio  Marco Petitta 《Environmental Earth Sciences》2014,71(4):1791-1807

Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.  相似文献   

Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer          下载免费PDF全文

Maurizio Gemelli  Massimo D'Orazio  Luigi Folco 《Geostandards and Geoanalytical Research》2015,39(1):55-69

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.  相似文献   

Chromium(VI) reduction by sulphur(IV) in aqueous solutions     

Maurizio Pettine  Daniele Tonnina  Frank J. Millero 《Marine Chemistry》2006,99(1-4):31

The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔH_app of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression